Scientific Program

Conference Series Ltd invites all the participants across the globe to attend 14th World Bioenergy Congress and Expo London, UK.

Day 2 :

  • Biofuels | Biomass | Bioethonal | Biogas
Location: Meeting Hall: Wright
Speaker

Chair

Bor-Yann Chen

National I-Lan University, Taiwan

Speaker
Biography:

Abstract:

Enzymatic catalysis for biodiesel production using low-cost, high free fatty acid oils has attracted much attention recently due mainly to economic issues, renewability, and sustainable benefits. The performance of a commercial, low-cost lipase (Eversa®, Novozymes) was investigated in the transesterification reaction for fatty acid ethyl esters (FAEE) production. In order to reduce the costs of industrial enzymatic biodiesel production, enzyme was used in its soluble, free form. The proposed approach, consisting in the transesterification of a low cost and sustainable Jatrpha oil, using (Eversa®, Novozymes) as catalyst with ethanol as alcohol to realize a completely green bio-process. The proposed approach uses an integrated process for the production of the FAEE ethyl esters which can be used as a promising substitute for conventional fuels, since it matches the European Biodiesel Standard EN 14214. The influence of variables such as temperature, catalyst concentration and alcohol/oil molar ratio on the production of both fractions has been studied and optimized by means of factorial design and response surface methodology (RSM). The obtained models are useful to determine the optimum operating conditions for an up-scaled industrial process, using a minimum number of experiments, with the consequent benefits from an economical point of view. However from a technical point of view, the highest possible yield for FAEE fraction should be targeted, consequently a catalyst concentration of 9.8% an alcohol/oil molar ratio of 6:1 and an operation temperature of 35°C should be chosen. According to these conditions, conversion rates of 98% for FAEE could be obtained. The preparation of the products is a green engineering process, clean, solvent-free, with a very selective catalyst that minimizes water and energy consumption and the downstream processing of the integrated process.
 

 

Speaker
Biography:

Muluken Eshetu Tefera has been working as a Lecturer at Jimma University, Jimma Institute of Technology under the school of Chemical Engineering since Aug 2014. He has been working on giving Lectures on fluid mechanics for chemical engineers, mass transfer unit operation and entrepreneurship for engineers courses, assisting undergraduate students in thermal and mass transfer unit operations laboratory, advising graduating students, mentoring industrial intern students and many more activities

Abstract:

In this study, methyl-ester, bioethanol and briquette samples were sequentially produced from spent coffee ground. The oil extracted from spent coffee ground with solvent extraction route at hexane to spent coffee ground ratio of 22.5 g/g with an extraction time of 30.4min resulting in 11.892% of oil yield. This was comparable with literature values and subsequently used for methyl-ester production experiments using a 1% by wt of NaOH at reaction temperatures and residence times ranging from 50 to 65°C and 20 to 60min, respectively. The optimization carried out using central composite design methodology gave 81.507% of methyl-ester yield at a reaction temperature of 57.133°C and reaction time (residence time) of 45.117 min with model determination coefficient (R2) of 0.9465 while the optimum reducing sugar yield for dilute acid hydrolysis experiments for ranges of operating parameters of temperature (70-100°C) and (1-3M ) of H2SO4 concentrations was found to be 39.161% at a temperature of 98.313°C and H2SO4 acid concentration of 2.962M.The central composite design optimization results for transesterification and dilute acid hydrolysis experiments were verified by running experiments at optimum conditions and in turn resulted 79.65% of biodiesel yield (out of 11.892 g of oil) and reducing sugars yield of 37.28% (out of the hydrolysate). This implied that the verification experimental results weren’t far from the predicted values so that the experimental results were sufficiently represented by the central composite design models. The bio ethanol produced by simple distillation having alcohol by volume yield of 55% can be considered as a good result and it can be easily concentrated to a fuel grade ethanol by using fractionating column. Moreover, the characteristics of the biodiesel produced were in good agreement with ASTM and EN standards. The end product of the process which is briquette has been produced from 75% wt of dilute acid hydrolysis residue and 25% wt of glycerol, resulted a calorific value of 13.35 MJ/kg, volatile matter value of 88.15%, ash content of 3.95%, and fixed carbon contents of 1.74% with its easily moldable physical status showed that it can as well be used for fueling purpose like firewood and charcoal. This study signifies the value addition that can be affected from spent coffee ground and the potential and results obtained in this regard are discussed. 

Speaker
Biography:

Wenquan Wang is a Senior Scientist of Genomics and Molecular Breeding for tropical crops as cassava, Professor of Biology and Agronomy in Hainan University, Huazhong Agricultural University, Executive Director of Key Laboratory of Tropical Crop Biology and Utilization of Genetic Resources. He is a Coordinator of National Key Basic Research Program (973) “The principal research on genetic improvement in cassava important tropical crop”. He got PhD in nutrition genetics in Chinese Agricultural University in 2000, and once being Senior Research Fellow in BTI, Cornell University during 2009-2010. In his academic career, dedicated to understanding molecular mechanism of carbohydrates accumulation in storage roots, developing new molecular tools to build up a whole genome resolution for elite varieties breeding in cassava and other tropical crops. The achievements include one third prize in National Science and Technology Innovation Award and two prizes of Provincial Scientific and Technology Award, two patents and above 200 publications include of articles published in Nature Comm., NAR, Scientific Reports, etc

Abstract:

Cassava (Manihot esculenta Crantz) is a vital important crop in the world because of its multiple utilization in food, feed, biofuel and green chemical materials in present and in the future. However, desirable elite varieties satisfied to food and industrial purpose still are bottlenecks in the field. We all know that the conventional breeding faced the big challenges due to the extremely heterozygosity of genome and too high cost to selection scale. How to pave a way towards to low-cost and high-throughput genotype selection will be an ideal blue map. Recent five years, our consortium made breakthroughs in several aspects like invented and patented a low cost and high throughput genotyping tool called the amplified fragment single nucleotide polymorphism and methylation-AFSM technology. It allows finding the SNV and methylation sites in whole genome level with very low cost and short time. Gained genotype information of over 800 cultivars and landraces of cassava including about 40 breeding parents. Main economical traits such as fresh root yield, dry matter yield, storage root quality, plant and leave types, tolerance to drought, cold and post-harvest physiological deterioration (PPD) tolerance to barren soil, whose correlated whole genome markers have been screened and produced a set of detectable breeding sites. A framework of genome selection breeding in cassava has been set up and based on it, several new elite varieties with characters of high yield, higher ethanol productivity, with erect plant type, tight and short storage root suitable for high dense planting and mechanic harvesting, tolerance to PPD and cold have been released.
 

 

Soo-Young No

Chungbuk National University, South Korea

Title: Utilization of higher alcohols to CI engines – A review
Speaker
Biography:

Soo-Young No has his expertise in atomization and sprays, combustion and emission characteristics in applying the liquid biofuels to internal combustion engines, particularly compression ignition engines. The review papers on liquid biofuels published by him include the biodiesel obtained from inedible vegetable oils, alcohols such as methanol, ethanol and butanol, bio-oil, straight vegetable oil, BTL diesel, hydrotreated vegetable oil. Further, the book titled on “Application of Liquid Biofuels to Internal Combustion Engines” written by him will be published on June 2019 at Springer.

Abstract:

The alcohols which could be used for automotive fuels were methanol, ethanol, propanol and biobutanol. However, recently the utilization of long-chain alcohols such as pentanol, hexanol, octanol, dodecanol and phytol has recently received significant attention as alternative fuels for diesel engines because they emit less greenhouse gases and harmful pollutants. Pentanol (C5H11OH) is one of higher alcohol with five carbons in its structure and has big potential as a blending agent with diesel fuel because of its high energy density, high cetane number, better blend stability and less hygroscopic nature than other widely studied lower alcohols such as methanol, ethanol and butanol. For the chemical kinetic oxidation models for pentanol isomers, fourteen detailed kinetic mechanism were developed, and five reduced kinetic mechanisms were suggested. Binary blends such as diesel/pentanol and biodiesel/ pentanol, ternary blends such as diesel/biodiesel /pentanol were widely studied in the conventional diesel engine. The pentanol/diesel blends coupled with EGR technology could simultaneously reduce NOx and soot emissions from CI engine. Further, diesel/pentanol blends generally produced higher CO and HC emissions than diesel fuel. However, CO and HC emissions were significantly reduced by mixing the cetane improver with the blends. Upto 45%~50% n-pentanol/diesel blends can be safely used in diesel engines without any engine modification or any additive. Very few information related to the application of pentanol to advanced CI engine is available in the literature. For ternary blends, diesel/biodiesel/pentanol blends were mainly studied by many investigators. The emission characteristics in CI engines in terms of CO, HC NOx and smoke opacity showed the different trend according to the pentanol proportion in ternary blends. Two different ways of hexanol such as co-surfactants and as blending agent include in the application of hexanol in diesel engine. Hexanol can replace diesel by up to 50% by volume and octanol can be used as neat octanol, octanol (up to 40%)/diesel blends, ternary blends and surfactants. Dodecanol upto 1.5% was employed as co-solvent to prevent the separation between ethanol or methanol and diesel phytol can be used as a blending agent by up to 20% in diesel engine. Fuel oil can be included in the higher alcohols because it is the mixture of mainly three alcohols of isopentanol, iso-butyl alcohol and ethyl alcohol. However, it will not be discussed here because it was used as a blend agent in SI engines.

Speaker
Biography:

Moses Ogun has his expertise in Environmental Technology. He is a Research Engineer at the Hamburg University of Technology. In his last research he worked on the photocatalysis of recalcitrant organics in wastewater effluent. For over four years now he has engaged himself in finding alternative approach for the treatment of deinking sludges produced by the wastepaper recycling industry. His strategies are mainly biological approach and reuse options.

Abstract:

Statement of problem: The wastepaper recycling industry produce different residues, among which is the deinking sludge (DS). The DS is generated from the deinking process and constitutes a major fraction of the residues generated by the European pulp and paper industry. The traditional treatment of DS by incineration is capital intensive due to energy requirement for dewatering and the need for complementary fuel source due to DS low calorific value. This could be replaced by a biotechnological approach. This study therefore investigated the biogas potential of different DS streams (different dewatering degrees) and the influence of its high calcium carbonate content of DS on its biogas potential. Method: Dewatered DS (solid fraction) sample from filter press and the filtrate (liquid fraction) were collected from a partner wastepaper recycling company in Germany. The solid fraction and the liquid fraction were mixed in proportion to realize DS with different water content [55 – 91% Fresh Mass]. Spiked samples of DS using deionized water, cellulose and calcium carbonate were prepared to simulate DS with varying calcium carbonate content [0– 40% Dry Matter]. Biogas potential was studied using a 1-Liter batch test system under mesophilic condition and ran for 21 days. Results and Conclusions: A specific biogas potential in the range 133- 230 NL/kg organic dry matters was observed for DS samples investigated. An optimal dewatering degree corresponding to a water content of about 70% fresh mass was identified for the biogas production of DS. No inhibitory influence was observed in the biogas potential of spiked DS samples due to the reported high calcium carbonate content of DS. This study confirms that DS is a potential bioresource for biogas production. Further optimization such as Nitrogen supplementation due to DS high C/N ratio can increase biogas yield

  • Biomass feed stocks for renewable energy generation | Processes for Bioenergy | Biofuels | Renewable energy | Biogas | Biomass
Location: Meeting Hall: Wright
Speaker

Chair

Soo-Young no

Chungbuk National University, South korea

Session Introduction

Bismark Ameyaw

University of Electronic Science and Technology of China, China

Title: Determinants of energy production from biomass: Multivariate Panel Data Evidence for IEA-30 Countries
Speaker
Biography:

Abstract:

The contemporary increase in worldwide population drives the generation of energy from conventional and unconventional sources. Energy generated from exhaustible resources endanger the environment and imperils economic development. However, production of energy from naturally replenished resources add-in to economic development and helps address issues of global warming and further grants energy security. This study seeks to investigate the determinants of biomass energy production for International Energy Administration (IEA)-30 countries for the period covering 2000-2015. In our analysis, Gross Domestic Product (GDP) per capita is used as a proxy for economic growth and energy imports is deemed as the main controlling factor.  Our panel fully modified and dynamic ordinary least squares regression shows a significant positive influence of total biomass energy production on economic growth. Thus, a percentage increase in primary biomass energy production increase GDP per capita by 0.04%-0.05%. For our panel vector error correction model based causality nexus, we notice that in both the short and long-run, there exist unidirectional causality running from economic growth and energy imports to total biomass energy production which supports the conservation hypothesis. The findings from the study indicates that economic growth and energy imports significantly influences total biomass energy production. This study guides policymakers in formulating a conclusive biomass energy and trade policies for sustainable economic growth. Synopsis of our Econometric Model Formulation: Our primary focus is to investigate the nexus between biomass energy production, energy imports and economic growth with a panel data fixed-effects regression model specified as follows: 0 1 2 it it it it Z Y C α β β ε = + + + (1) Where  denotes the dependent variable gross domestic product per capita (GDPC) ;  represents total biomass energy produced;  represents each IEA member country-level control variables;  is the intercept or constant and  and are the parameters; is the stochastic error term;  is the subscript of each IEA member states where , and  is the subscript of each IEA member state time dimensions where . More specifically, we explore the relationship between biomass energy production (TBEP), energy imports (EI) and GDPC by employing Granger causality test based on panel vector error correction model (PVECM). For our stationarity analysis, we first employ Im, Pesaran and Shin (IPS) test developed by Im et al. which allows for heterogeneous autoregressive coefficients. We formulate our mathematical model as: 1it i it i it it z vz Y δε − = + + (2) Where itY represents our predictor variables comprising individual time trend; autoregressive coefficients is represented by iv ; and it ε represent the stationary stochastic error terms. As the IPS ensures various orders of serial correlation by averaging the augmented Dickey-Fuller (ADF) unit root test, we formulate our stochastic stationary error term as:   
1
iv it ix it x it x ε φ ε µ − = = + ∑
(3) Therefore, by substituting (3) into (2), our mathematical formulation becomes: 1
1
iv it i it ix it x i it it x z vz Y φ ε δ µ −− = = + + + ∑ (4) Where the number of lags in ADF regression is represented by. We propose our null hypothesis to be a case where there exists a unit root in each series of our panel data sets whereas alternative hypothesis supposes that at least one individual series in the panel data is stationary. Besides Phillips-Perron (PP), Augmented Dickey-Fuller and Levin, Lin & Chu (LLC) stationarity test are executed.
 

 

Biography:

Abstract:

Lignocellulosic biomass serves as a reservoir of sugars, which could be used as a potential source for alternative energy and value-added products. Since, the lignocellulose is made up of a complex framework of various components, utilizing it as a readily available material for value addition is a tough task. Usage of chemicals coupled with physical or biological treatments provide a promising way of accessing lignocellulose. In this study, bambara biomass was chosen as a raw material; comprehensive characterization of the biomass was performed to evaluate their potential as a new lignocellulosic feedstock. Xylan, the major hemicellulose component of the biomass was chosen as the source of interest and was extracted by alkaline method. The alkaline extraction of biomass reduced the damage of polysaccharide chains, which could further be explored for desirable product synthesis. The extracted xylan was characterized by NMR and monosaccharide analysis and confirmed as glucuronoxylan. The bambara xylan was further subjected to hydrolysis by the enzyme β-xylanase, yielding Xylooligosaccharides (XOS), with properties suited for use as a prebiotic. Further, a novel prebiotic spread using Bambara and Amadumbe starch was prepared which contained XOS as the dietary fiber. The new spread enriched with prebiotic offers consumers the benefit of having a healthy diet with improved dietary fiber

Biography:

L E Macaskie did her BSc and PhD in Microbial Biochemistry (University of London) in the 1970s, moving to the University of Oxford (postdoctoral, then faculty staff in Department of Biochemistry) until 1991 when she took up a lectureship, then personal Chair, at the University of Birmingham in Applied Microbiology. Her dual interests center on bacterially manufactured nanoparticles and bio-nano minerals for nuclear decontamination processes and precious metal neo-catalysts for clean energy, green chemistry and environment. Needing hydrogen to feed her bacteria. She developed a process to make bio-H2 via fermentation of food wastes, outperforming other renewable energy processes in terms of energy balance. 

Abstract:

https://bioenergy.insightconferences.comBacteria can manufacture supported nano-catalysts from solutions of precious metals (PMs), waste leachates and industrial processing solutions as an economic alternative to the use of primary-sourced PM catalysts in high volume/low value applications. Metal deposition occurs via nucleation of soluble metal ions to cellular ligands followed by enzymatically-catalysed growth of nanoparticles (NPs), to form templated, structured nanomaterial. This can self-immobilize onto a carrier for easy catalyst recovery, multiple re-use and in continuous-flow processes. Monometallic structures like Pd-NPs have multiple applications but faster reactions and higher selectivity can be achieved with a second metal to make alloys or core-shell nano-patterned structures. The second metal coupling is abiotic; importantly, no live bacteria remain in the material, while the catalysts can be made directly from highly acidic leachates in order to ‘bio-refine’ precious metal (PM) scraps, overcoming the economic barrier to use of PMs for large or sacrificial operations. Examples will describe the use of such neo-catalysts in fuel cells and also applications in upgrading of intermediates produced in the thermochemical processing of organic materials to a platform chemical and fuel precursor; the use of catalysts bio-refined from road dusts in the catalytic upgrading of heavy fossil oils (reduced viscosity, levels of impurities and coking)1 and in the catalytic hydrodeoxygenation of pyrolysis oil from biomass  2. Throughout, the bio-derived catalysts performed comparably to commercial catalysts and favourable oil distillation curves were obtained. In addition, when upgrading 5-hydroxymethyl furfural extracted from biomass hydrolysate the commercial catalyst was ineffective although a bio-Pd/Ru equivalent achieved the conversion. For economy at scale, similar results were obtained using ‘second life’ bacteria left over from another bioprocess, while the catalysts were bio-refined from PMs from high volume wastes (road dusts). The latter has been subjected to a life cycle assessment showing process viability at scale.
 

Speaker
Biography:

Ramachandran Sivaramakrishnan is currently a Senior Post-Doctoral Research in the Cyanobacterial Biotechnology (Biochem dept.) Group Led by Dr. Aran Incharoensakdi at Chulalongkorn University, Bangkok, Thailand. His research interests include the production of biofuels, value-added products, understanding the mechanism of biofuel productions and exploring value-added products. Before joining Dr. Aran Incharoensakdi lab, he worked as a Junior research fellow in the Department of Chemical Engineering at Anna University, India. 

Abstract:

Environmental problems coupled with rapid depletion of fossil fuel and its resources prompted researchers to find alternative renewable resources and its commercialization. The biomass from microalgae with high oil content is a promising feedstock for the renewable resources. Compared with plants, microalgae can produce more oil per hectare with a shorter production cycle. The coupling of algae biofuels with high value compounds production widens the market opportunities which fits well with a recent trend of biorefinery concept. For biorefinery approach, it is essential to select the microalgae which contain high amounts of organic matters such as lipids and carbohydrates which can be used for biorefinery approaches. The present study focuses on the concomitant production of methyl ester and É›-polylysine from microalgae feedstock. The harvesting efficiency of Botryococcus sp. was increased up to 93% by treatment with a flocculant FeCl3 at 100 mg/L for 30 min. The DMC (dimethyl carbonate) mediated enzyme catalyzed in-situ transesterification of Botryococcus sp. yielded the maximum methyl esters of 93% under optimized conditions. The spent biomass was further hydrolyzed using acid and the hydrolyzate obtained was used to produce value-added product e-polylysine using Streptomomyces sp. The key components of sugar and MgSO4 involved in the ε-polylysine production were optimized whereby the maximum ε-polylysine production was achieved at 50 g/L sugars and 0.3 g/L MgSO4. The ε-polylysine production was further improved by the supplementation of important acids (lysine and aspartate) and TCA cycle intermediates (citric acid and α-ketoglutaric acid). The maximum production of 2.31 g/L was found with 4 mM citric acid supplementation after 130h. The present study demonstrated the effective harvesting method of microalgae and integrated production of methyl ester and ε-polylysine as a biorefinery approach. The promising path of the biorefinery concept in the present study will help to develop the economy based sustainable fuels and value-added compounds production in the near future. 

Amos Oppong

University of Electronic Science and Technology of China, China

Title: Energy policies needed to transition to a green economy based on high-accuracy forecasts
Biography:

Amos Oppong is a Doctoral Researcher at the School of Management and Economics (SME) of the University of Electronic Science and Technology of China (UESTC), and a Member of the International Association of Energy Economists (IAEE). He specializes in environmental energy and economic modelling and forecasting. 

Abstract:

Renewable energy (including bioenergy) is a key for economic developmental consistency and supply is necessary for keeping countries on a sustained growth path. In order to minimize cost due to over (excess supply) and/ or under supply (shortage), policymakers and stakeholders leverage on business-as-usual (BAU) energy demand projections as benchmarks to design and implement efficient policies. Existing high-profile energy demand forecasting models (such as NEMS) achieve relatively high accuracies for short- and medium-term projections but records high forecast inaccuracies when utilized for long term cases due to the massive assumption dependent explanatory variables whose assumptions often deviate from realized levels but are pivotal to the core forecasting modules. Here, we implement a relatively high-accuracy level, trend and seasonality consistent technique that is devoid of assumption driven variables for BAU long-term energy demand forecasting. We utilize the technique to forecast bioenergy and total primary energy supply in the USA. The results suggest that for the 2012-2016 fiveyear forecast, the accuracy of the proposed technique strikingly outperform the regression and double exponential smoothing (DES) benchmark models and record significant improvement up to ~10- fold on NEMS related reference case forecast as reported in Annual Energy Outlook 2011 (AEO2011) and AEO2012. Outputs from applying the proposed high-accuracy technique for long-term production and consumption projections show that total renewable energies will account for ~15.77% out of the expected ~101.75 quadrillion Btu total primary energy consumption in 2035; thus radical and revolutionary energy policies are required for USA to achieve the ‘100% renewables by 2035’ target approved by the U.S. Conference of Mayors in June 2017

Stephen Aarnold

Great Driffield, E Riding of Yorkshire, UK

Title: Straw pelleting
Biography:

Abstract:

  • Poster presentation
Location: Meeting Hall: Wright
Speaker

Chair

Grace N Ijoma

University of South Africa, South Africa

Session Introduction

Gema Sevilla Toboso

Centro Nacional del Hidrógeno (CNH2), Spain

Title: Agro-food industry waste for BioHydrogen production by dark fermentation
Speaker
Biography:

Gema Sevilla Toboso has her expertise in improving the environment. Her evaluation based on agro-food industry waste from Castilla-La Mancha creates new ways to produce hydrogen and thus improve the environment through the generation of a fuel that does not produce greenhouse gases while treating this waste. Her investigation is carried out in CNH2, a National Research Centre at the service of the entire Scientific, Technology and Industrial Community. 

Abstract:

Increasing demand for energy, depletion of primary energy sources (i.e., coal and oil) and environmental degradation have made the production of energy from alternative nonconventional sources essential. In the same way, recent trends in food production have led to an increase in the generation of wastes during food processing, that needs further management to avoid environmental problems. Therefore, hydrogen produced from renewable sources could play an important role for future energy economy as clean, CO2 neutral and environmentally friendly energy carrier. Hydrogen is easily used in fuel cells for electricity production, whose high energy yield of 122 kJ g− 1, which is 2.75 times greater than known hydrocarbon fuels, allows its use as a fuel for transportation. In addition, it can be stored not only chemically but also physiochemically in various solid and liquid composites. Hydrogen can be produced from a wide-ranging variety of primary energy sources and different production technologies. However, currently most of it is produced by Steam Reforming from nonrenewable feedstock, producing high greenhouse gas emissions. In contrast, fermentative hydrogen production can utilize renewable carbohydrate-based substrates, such as waste biomass from agricultural sectors. Furthermore, this process occurs at lower temperatures and pressures, and is therefore less energy-intensive than chemical and electrochemical processes. So, abundant biomass from various industries could be a sustainable source for biohydrogen (hydrogen produced by living organisms) where combination of waste treatment and energy production would be an advantage. In this work different types of agro-food industry waste from Castilla- La Mancha (dairy wastes, beer lees, winery waste and mushroom waste) have been studied in order to determine the substrate with the highest biohydrogen production by dark fermentation. For this purpose, different experiments have been carried out with the aim of quantify certain characteristics of substrates, like carbohydrate content and trace elements, that influence in the H2 yield. 

A V Bailey

Rochester Institute of Technology, USA

Title: Clean energy generation using fuel cells
Speaker
Biography:

A V Bailey PhD and D.Sc., (Chemistry) is a Principal Lecturer in the School of Chemistry and Materials Science of RIT, USA actively teaching undergraduate courses ranging from General & Analytical Chemistry through ‘Clean energy” courses including three online courses, which she designed. She holds forty patents and have authored over 80 scientific publications, including four books. As a member of clean energy team, she developed and taught a new lecture and lab courses clean energy: hydrogen/fuel cells based on the written textbooks. She has advised undergraduate students doing research in the field of polymer membranes for fuel cells. As a PI of five exelon constellation company grants education program about electricity generation using fuel cells 2015 -2019, she conducts training sessions to NY State High School Teachers. She was nominated for the outstanding teaching award for RIT Non-Tenure-Track Faculty and for the Provost's Innovative Teaching with Technology Award. 

Abstract:

With the increasing effect of climate change on our environment, there is a demand for clean energy which does not emit carbon dioxide. One solution is the use of gaseous hydrogen powered fuel cells to generate electricity with water as the only product. The future of our universe depends on educating teachers and students to be more proactive with clean energy. A combination of free on-line webinars and face-to-face work on lab assignments for high school teachers and students were offered. The sessions covered the topics like global warming; clean energy sources; hydrogen as a fuel and an energy carrier; fundamentals of electrochemistry; electricity generation using fuel cells; fuel cell construction; hydrogen properties, storage, production and hydrogen infrastructure. During the lab sessions, the participants did hands on experiments associated with fuel cell construction and use for electricity generation; measuring the amount of hydrogen generated and parameters of electricity generated and solar electrolysis of water. As part of this educational experience, the high school teachers were helped with incorporating the materials into their classrooms.
 

Jose C. Merchuk

Ben Gurion university of negev, Israel

Title: Biomass production methods: A review
Biography:

Ben-Gurion University of the Negev & Azrieli College of Engineering • Chemical Engineering & Pharmaceutical Engineering.

Abstract:

It is difficult to represent the behavior of a photosynthetic culture by simple kinetic expressions. This is specially so when the dynamic behavior of the cultures has to be considered, because of the interaction of fluid dynamics with photosynthesis. All of the mathematical models of photosynthesis available in the literature are based on the lumping of a large amount of biochemical reactions into simpler steps or into hypothetical concepts, which aim at representing the behavior of the actual biochemical apparatus. The selection of a model is, thus, the result of the compromise between the ‘loyalties to biology’, that is, to the elements of the biochemical steps that are quite known in the photosynthetic process, and the computational burden resulting of a complex mathematical formulation. Photosynthetic cells change the rate of biomass synthesis as the irradiance that they perceive changes. Because of this, data are collected usually after keeping the culture at a constant irradiance during considerable time. During this time, the cells adequate its photosynthetic elements to those conditions and this is detected as a change not only in production rate, but also in the cell composition, mainly as chlorophyll a (Chla) concentration change. This is called photo acclimation or photoadaptation.  The minimal requirement for the design of a PBR is the P–I curve, that is, the dependence of the photosynthesis rate on irradiance, with easily measurable parameters usually called α, the initial photosynthesis rate, and Pm, the maximal photosynthesis rate, at certain irradiance Is. Thus, the parameters of the curve, in spite of being empirically determined, can be associated to the growth process and to the behavior of the culture, which depend on its physiological state. P is usually given in terms of biomass produced per unit time and unit volume (or mass) of the culture, or per unit illuminated surface. The basic  approach is valid only for a photo acclimated system, that is, a system that has been kept for sufficient time at each of the irradiances. If the P–I curve is the simplest way of representing the kinetics of photosynthesis, on the other end of the range there is a group of much more sophisticated models that can be called physiological, aiming at the representation of the dynamic behavior of photosynthetic cells, and proposing approximations to the mechanism operating inside the cells which depends on their capacity of adaptation to different illumination intensities. Those models try to express the dynamics of a photosynthetic culture taking into account a considerable amount of variables in addition of the obvious (carbon source and light), and among them various substrates that algae require for growth, as nitrate and phosphate, and also intracellular concentrations of Chla, the extent of light-damaged protein D1 in photosystem II (PSII), nitrogen and carbon content in the cell, etc. The goal of those advanced models is representing mathematically the actual physiology of the photosynthetic cells. An expectable drawback in this type of models is the large amount of parameters that have to be adjusted. There is still another group of models of photosynthesis that can be situated between the previous two extremes. Those are the models using the concept of photosynthetic unit (PSU), also called photosynthetic factories (PSUs).2,4,45– 52 These models are especially instrumental in representing the dynamics of the photobioreactors, because they do not aim at describing the physiology of the cell but the behavior of the algal culture. The main variable considered is the light intensity, which is usually the limiting substrate in dense cultures as those focused for industrial production. It is assumed that all the other substrates are provided at sufficient rate and being in excess do not need to be taken as variables. The engineering aspects of the addition of those nutrients to the bioreactor are simply based on stoichiometry. There is a wide range of devices that have been used for the modeling of PBRs. Many of those devices are the result of ingenious invention and empirical trial & error processes. Only a small part of those have been developed via modelling and using adequate kinetic representations of the biomass growth. The poster will review critically those systems.

Biography:

Alan J Stephen is a PhD student at the University of Birmingham with the CDT in Fuel cells and their Fuels. His work focuses on utilising bacteria to synthesize precious metal nanoparticles to use as catalysts in a fuel cell.

Abstract:

Biosynthesis of nanoparticles (NP) is emerging as a new, eco-friendly and high yield alternative to chemical NP synthesis. Various microbial strains (including E. coli) have been used to synthesize bio-nanoparticles (BioNPs) from a variety of elements including precious metals such as platinum, palladium and gold. Pt and Pd nanoparticles have been extensively investigated as electrocatalysts in Polymer Electrolyte Membrane Fuel Cells (PEMFC) and such BioNPs could work effectively as electro-catalysts for PEMFC. However, all these processes require highly destructive methods for NP extraction before they use as a catalyst, e.g., E. coli-Pt catalyst was comparable to commercial counterparts, but chemical NP extraction was slow (~1 month) which destroyed the bio-scaffold and increased particle sizes. The problematic inherent resistivity of native E. coli biomass was overcome by use of E. coli -Pd NPs which formed primarily on the cell surface to act as a conductive shell, but substitution of Pd for Pt compromised the power output. A sequential synthesis of palladium and then platinum on E. coli made a bimetallic E. coli-Pt/Pd catalyst with activities higher than its single metal counterparts. A suite of catalysts with a range of metal loadings was made and the materials were characterised using high resolution STEM with energy dispersive X-ray microanalysis (EDX) mapping, and XRD and XPS analyses, alongside tests ex-situ in a three electrode cell to evaluate their catalytic activities and durabilities as compared to commercial catalysts.
 

 

Biography:

S A Archer is a PhD candidate, studying for a Doctorate in Hydrogen, Fuel Cells and their Applications, whilst working with the Resource Recovery from Wastes programme (RRfW). Her knowledge and skills involve the application of life cycle thinking and environmental impact assessments to produce liquid and gaseous fuel products from biomass and waste residues in addition to biorefined neo-catalysts from resources recovered from waste streams. Her work aims to conduct an LCA on the catalytic upgrading of both heavy fossil oil and pyrolysis oils from dry biomass, comparing commercial and biocatalysts. The environmental impact for each pathway will be identified within a ‘well to gate’ (cradle to gate) system boundary, alongside an additional fuel use analysis separate from the LCA. 

Abstract:

As fossil fuels deplete, attention is turning intensively by carbon emitting and environmentally damaging extraction methods to use heavy oils and bitumens. In situ catalytic upgrading can use platinum group metals (PGMs) in a once through process, which decreases oil viscosity in situ and is cleaner, whilst being prohibitively expensive. The once through process also wastes limited PGM resources. For new technologies to become market competitors, they must be either substantially cheaper than their competitors or achieve an outcome that is difficult by current methods. Classical life cycle analysis (LCA) focuses on salient ecological impacts but bypasses key economic aspects and does not assign quantifiable benefits. This research factors in the benefits of environmental protection, reduced CO2 emissions and the environmental impact of oil extraction and fuel production using a ‘well to gate’ LCA (also known as cradle to gate), as well as the economics involving the mitigation of ‘landfill gate fees’ for waste resources and social cost of carbon. The case histories evaluated the involved catalysts biorefined from wastes for application in cleaner extraction, upgrading and processing of heavy fossil and pyrolysis bio-oils, with comparison to their commercial counterparts. Each oil case history has been analysed with both a commercial catalyst and a biocatalyst, which are assessed as an alternative catalyst in oil ratios (%eq. of g/g). Pyrolysis bio-oils from waste wood and algal sources were successfully found to be upgradable using both catalysts. They produce carbon-neutral fuels because of carbon sequestration during photosynthetic biomass growth, and the bacterial components supporting the catalyst become assimilated into the fuel.
 

Speaker
Biography:

Jai Hyun Park is a PhD candidate in Gyeongsang National University, South Korea. His studies are in growing media for growing various plants. He is interested in biomass and bio-ethanol production. 

Abstract:

Many road slopes have been created along with many road works. Since these road slopes have problems of landslides and soil erosion, there are many studies on road slope greening. However, it is difficult to grow plants on a general slope. Generally, growing medium is used to replace soil for plant growth and in recent years, many studies have been conducted to produce the growing medium using various materials such as agricultural byproducts and sewage sludge. Since, the study on the road slope greening to use this growing medium is quite limited, we produce the growing media using woody biomass and apply the prepared growing media to the preliminary slope to determine the germination of Lotus corniculatus. The growing media was prepared by mixing woody biomass, peat, perlite and sodium nitrate. Soil was used as a control. Soil, soil and growing media mixture (1:1, w/w) and growing media were applied to slope to observe physical and chemical properties and germination of Lotus corniculatus. As a result, physical properties (moisture content, bulk density and porosity) were improved by using growing media to compare soil for plant growth. Among the chemical properties, the organic matter, available phosphate and CEC were also higher in the using growing media than soil. However, the germination of Lotus corniculatus was the highest in the mixture of soil and growing media followed by the higher in the soil. The lowest germination was in the growing media. In conclusion, when the results of physical and chemical properties and germination, it was confirmed that the mixture of soil and the growing media was most suitable for plant growth on the slope. 

Speaker
Biography:

Si Young Ha is student and PhD candidate of Gyeongsang National University in South Korea. She had retained a keen interest in applied and various fields of biomass. In particular, she has been studying the chemistry of woody biomass and their efficacy in treatment of vitiligo or atopic for a long time. She also has experience in poster presentation in the symposium on biotechnology for fuels and chemicals (2016) and bioenergy conference (2017

Abstract:

More recently, Cordyceps militaris has been widely used due to its folkloric activities, which are not based on scientific studies. Cordycepin (3′-deoxyadenosine), a metabolite of C. militaris, has been showed to inhibit the growth of various tumor cells. Previous work reported the isolation of cordycepin from liquid culture medium of C. militaris and its pharmacological functions. But, as far as we know, there is limited knowledge about the light emitting diode (LED) condition for cordycepin production by C. militaris. In this paper, the effects of LED were focused in order to improve the cordycepin production by submerged cultivation of C. militaris. For this experiment, mycelial cultivation was performed in a shaking incubator at 24°C, 100 RPM for 5 days and the medium was sabouraud dextrose broth (pH 5.6). The red, green and blue were used for the LED and dark culture and fluorescent lamp were used as the control. This results, C. militaris showed the highest mycelial weight when green light was irradiated on the other hand, when irradiated with blue light, the content of cordycepin is about 4 times higher than that of fluorescent lamp in the cultures of C. militaris. In addition, the highest content of cordycepin was observed when irradiated for 6 h/day for 3 days. Interestingly, mycelial weight and cordycepin content were inversely related. The information obtained is considered fundamental and useful to the development of C. militaris cultivation process for efficient production of cordycepin on a large scale.